2 edition of Aminoboration and related reactions P found in the catalog.
Aminoboration and related reactions P
R. H. Cragg
|Statement||Supervised by: Lappert, M.F..|
|Contributions||Lappert, M. F., Supervisor., Chemistry.|
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Chloroboration and allied reactions of unsaturated compounds. Part III. Aminoboration and alkoxyboration of isocyanates and isothiocyanates R. Cragg, M. Lappert and B. Tilley Abstract. The first page of this article is displayed as the abstract.
Cited by: Malkanthi K. Karunananda and Neal P. Mankad. Heterobimetallic H2 Addition and Alkene/Alkane Elimination Reactions Related to the Mechanism of E-Selective Alkyne Semihydrogenation. Organometallics36 (1), DOI: /met.6bCited by: We report here a facile B(C6F5)3 catalyzed trans-aminoboration of internal alkynes, furnishing 3-position borylated indoles at ambient temperature.
This reaction proceeds with the breaking of a B–N bond and the formation of N–C and B–C bonds to produce indole and derivatives in one step. It works well for various boron reagents and by: This communication demonstrates the first catalytic aminoboration of C–C π bonds by B–N σ bonds and its application Aminoboration and related reactions P book the synthesis of 3-borylated indoles.
The regiochemistry and broad functional group compatibility of this addition reaction enable substitution patterns that are incompatible with major competing technologies. This aminoboration reaction effects the formation of C–B Cited by: Learn more about these metrics Article Views are the COUNTER-compliant sum of full text article downloads since November (both PDF and HTML) across all institutions and individuals.
These metrics are regularly updated to reflect usage leading up to the last few days. The Altmetric Attention Score is a quantitative measure of the attention that a research article has received by: A copper-catalyzed regioselective, stereospecific, and enantioselective aminoboration reaction of alkenes electrophilic amination strategy.
Further development of related C–N bond-forming processes is ongoing in our laboratory. Organotransition Metal Chemistry: From Bonding to Catalysis, Vol. 1, p.University Science Books.
A copper-catalyzed aminoboration of alkenyl dan boronates (dan = 1,8-diaminonaphthyl) with diboron reagents and hydroxylamines has been developed. The reaction proceeds regio- and stereoselectively to form the corresponding β-boryl-α-aminoboronic acid derivatives of potent interest in medicinal chemistry.
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